HERETIC-NMR법을 이용한 인의 정량분석
Quantitative analysis of phosphorus by HERETIC-NMR method
임헌성(한국화학연구원 화학분석센터); 박찬조(한국화학연구원 화학분석센터); 이석근(한국화학연구원 화학분석센터)
21권 5호, 438~441쪽
초록
We have developed an alternative to the internal chemical reference based on a calibrated reference signal which is not a real NMR line but an electronically produced signal (HERETIC) and determined the phosphorus concentration using this method. The area ratio of HERETIC and sample peaks obtained from the standard samples was used to measure the concentrations of different samples directly. The analysis of phosphorus by this method showed the excellent linear regression coefficient (R2=0.9999) for the concentration range from 20 ppm to 500 ppm with HERETIC peak as reference.
Abstract
We have developed an alternative to the internal chemical reference based on a calibrated reference signal which is not a real NMR line but an electronically produced signal (HERETIC) and determined the phosphorus concentration using this method. The area ratio of HERETIC and sample peaks obtained from the standard samples was used to measure the concentrations of different samples directly. The analysis of phosphorus by this method showed the excellent linear regression coefficient (R2=0.9999) for the concentration range from 20 ppm to 500 ppm with HERETIC peak as reference.
- 발행기관:
- 한국분석과학회
- 분류:
- 화학